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This is normal behavior – Because the system will always boot up as it was when shut down – which will most likely include changes made since the last scene you recalled. So it might look like you have scene 20 say on the system but it will actually be scene 20 + any mix changes since the last scene recall. So it isn’t actually scene 20 at all – it is just the last mixer state when shut down. If when you reboot you actually want scene 20 then you will still need to select and recall it.
Hope that helps